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![]() These trends explain the periodicity observed in the elemental properties of atomic radius, ionization energy, electron affinity, and electronegativity. This happens because the number of filled principal energy levels (which shield the outermost electrons from attraction to the nucleus) increases downward within each group. Second, moving down a column in the periodic table, the outermost electrons become less tightly bound to the nucleus. Valence electrons are the electrons present in the outermost shell of an atom. The electron configuration of a oxygen atom is. While core electrons are not involved in bonding, they influence the chemical reactivity of an atom. As this happens, the electrons of the outermost shell experience increasingly strong nuclear attraction, so the electrons become closer to the nucleus and more tightly bound to it. Generally, valence electrons can participate in the formation of chemical bonding, but core electrons cannot. First, electrons are added one at a time moving from left to right across a period. 9.9: Periodic Trends - Atomic Size, Ionization. The chemical properties of elements are determined primarily by the number and distribution of valence electrons. Electron configurations can be predicted by the position of an atom on the periodic table. In addition to this activity, there are two other important trends. The arrangement of electrons in atoms is responsible for the shape of the periodic table. Stable octets are seen in the inert gases, or noble gases, of Group VIII of the periodic table. Elements tend to gain or lose valence electrons to achieve stable octet formation. These trends can be predicted merely by examing the periodic table and can be explained and understood by analyzing the electron configurations of the elements. The periodic table arranges the elements by periodic properties, which are recurring trends in physical and chemical characteristics. ![]() ![]() ![]() In November 2023, Rockstar president Sam Houser announced the first trailer would release in early December to celebrate the company's 25th anniversary. In July, Rockstar announced Red Dead Online would not receive more major updates as development resources were withdrawn to focus on the upcoming game industry sources stated Rockstar reallocated resources after planned remasters of Grand Theft Auto IV (2008) and Red Dead Redemption (2010) were paused due to the backlash received by Grand Theft Auto: The Trilogy – The Definitive Edition (2021). On 4 February 2022, Rockstar confirmed development was "well underway". An individual referencing the game received media attention for interrupting several live stage and television shows. The game became highly anticipated in the years before its announcement, and journalists noted some fans became frustrated by Rockstar Games's continued silence, particularly after they announced a re-release of Grand Theft Auto V in 2020. In 2022, Schreier reported the game entered development in 2014 and would feature two Bonnie and Clyde-inspired protagonists, including a Latina woman, and claimed the developers were cautiously subverting the series' trend of joking about marginalised groups. In 2021, Tom Henderson claimed the game's map could evolve akin to Fortnite Battle Royale. ![]() In 2020, journalist Jason Schreier reported the game was "early in development" as "a moderately sized release" that would expand over time, to avoid its predecessors' developer crunch. In 2018, The Know reported the game, code-named Project Americas, would be set primarily in Vice City and partly in South America with a female protagonist. Developmentįollowing Grand Theft Auto V 's 2013 release, Rockstar North's then-president Leslie Benzies said the company had "some ideas" for the series' next entry. The story follows a criminal duo: Lucia, the series' first female protagonist since 2000, and her male partner the first trailer depicts Lucia as a prison inmate, and later evading custody with her partner. The game world parodies contemporary American culture, with satirical depictions of social media and influencer culture, and references to Internet memes such as the Florida Man. ![]() Vice City was previously featured in Grand Theft Auto (1997) and as the main setting of Grand Theft Auto: Vice City (2002) and Grand Theft Auto: Vice City Stories (2006). Grand Theft Auto VI is an action-adventure game set in the fictional open world state of Leonida-based on Florida-which includes Vice City, a fictionalised version of Miami. The game was formally revealed in December 2023 and is scheduled to be released in 2025 for the PlayStation 5 and Xbox Series X/S. That September, footage from unfinished versions was leaked online in what journalists described as one of the biggest leaks in the history of the video game industry. įollowing years of speculation and anticipation, Rockstar confirmed in February 2022 that the game was in development. ![]() Set within the fictional open world state of Leonida-based on Florida-and its Miami-inspired Vice City, the story is expected to follow the criminal duo of Lucia and her male partner. It is due to be the eighth main Grand Theft Auto game, following Grand Theft Auto V (2013), and the sixteenth entry overall. Grand Theft Auto VI is an upcoming action-adventure game in development by Rockstar Games. ![]() ![]() ![]() However, you may be able to add them depending on your level of experience and the type of role you’re seeking. Most of the time, you don’t need to include projects or interests/hobbies on your resume. Should you add projects, interests, or hobbies to your nursing resume? Worked in a setting with a 6:1 patient-nurse ratio, receiving 400+ visitors per day.So, it’s lucrative to include the number of patients you served per a specific amount of time. The number of patients you serve per day can help potential employers gauge whether you will cope well under pressure. Some of the health facilities labor under tremendous pressure. Trained 75% of new hires on pre and postoperative care >20 days per month.Number of clinical training sessions per day.In that case, you can indicate the number of training sessions you conducted per day in your previous employment. Suppose the nursing job description asks for a training specialist who can train other nurses. So, whenever you can, you should quantify your impact and achievements.įor instance, if you say you “served many patients daily,” a potential employer might wonder about the exact number because ‘many’ is a relative term. Instead, they want to see supporting details. When preparing your resume, remember that no employer wants to waste time reading vague statements about your performance. ![]() Specific, pertinent job duties show employers your skills and can also help you pass the ATS two thumbs up for this one!.Oversaw the safety of patients in the healthcare facility by formulating risk mitigation measures in the unit.Again, this uses an action verb but furthermore, it describes exactly what the candidate provided (primary care training). ![]()
![]() ![]() Office 2007 is incompatible with Windows 2000 and earlier versions of Windows. The new formats are intended to facilitate the sharing of information between programs, improve security, reduce the size of documents, and enable new recovery scenarios. Office 2007 also introduced Office Open XML file formats as the default file formats in Excel, PowerPoint, and Word. Office 2007 introduced a new graphical user interface called the Fluent User Interface, which uses ribbons and an Office menu instead of menu bars and toolbars. The Mac OS X equivalent, Microsoft Office 2008 for Mac, was released on January 15, 2008. The ninth major release of Office for Windows, Office 2007 was preceded by Office 2003 and succeeded by Office 2010. It was released to manufacturing on Novemit was subsequently made available to volume license customers on November 30, 2006, and later to retail on January 30, 2007, shortly after the completion of Windows Vista. It was officially revealed on Maand was the 12th version of Microsoft Office. Microsoft Office 2007 (codenamed Office 12 ) is an office suite for Windows, developed and published by Microsoft. English, Arabic, Simplified Chinese, Traditional Chinese, Czech, Danish, Dutch, Finnish, French, German, Greek, Hebrew, Hindi, Hungarian, Italian, Japanese, Korean, Lithuanian, Norwegian (Bokmål), Polish, Portuguese, Romanian, Russian, Slovak, Slovenian, Spanish, Swedish, Thai, Turkish, and Ukrainian. ![]() ![]() ![]() To use this pdf document, print it out here and simply color in the coins in the mason jar that corresponds to the amount you save. If you’re still working on debt payoff goals, it’s wise, to begin with, a starter emergency fund of $1,000, which this printable will help you save. Well, now you can plan for those and use this saving tracker to save a small amount for emergencies. We all know how unplanned expenses can derail our plans and it’s no fun our total savings are reduced due to an emergency. Here are the free printable savings tracker coloring pages that are going to help you take your savings from zero to goal reached in no time.ġ – Emergency Fund Printable Savings Tracker Coloring Page If you do, just know you’ll be my role model, okay? But let me stop rambling and get on to the fun part. Yes, that’s right! These are free charts for your own personal use!ĭo you know what the best part is, you can download all these money trackers if you’re feeling fancy and save till your heart is content. All you do is click on the images or links at no additional cost. The choices are endless.Įach of the goal trackers comes in a pdf format and is available for instant download. You can hang it on the refrigerator, or your vision board, or you can even place it in your personal finance binder. Then you just print it out and put it somewhere you’ll see it every day. Simple, the first step is to decide on a savings goal. These posts are full of ideas that will help you find ways to save that can be put towards your savings goals. Check out these blog posts, 162 Frugal Living Tips to Try and The Top 12 Ways You Can Earn Gift Cards for Free. Even better, find different ways to earn extra in your spare time. Oftentimes, a savings goal is just the motivation we need to search for extra ways to save money on bills we are already paying or to save on things we may be purchasing. Let’s be clear, not all of us may want a side hustle or more work to do, but that doesn’t mean you should skip out on free money either. You’ll be motivated to find extra money to reach your goals. Some may find it challenging to focus on many different savings goals, but with a fun and cute savings goal tracker, the daily reminder can help you visually organize your goals and take small, tangible steps in reaching them. You can easily manage multiple new savings goals. If you’ve never kept track of your money before, check out How To Track Your Monthly Expenses So You Can Stick With Your Budget. In order to reach your goals and stash away as much money as you can in your piggy bank, you’ll be forced to second guess the small amounts you may be spending on random things. Here are just a few clear-cut examples of all the benefits you stand to reap if you choose to use one of these coloring sheets to track your savings… You’ll have a visual reminder of all the hard work you’ve put in and you can feel proud of any amount of money you’ve managed to stash away in your bank accounts. ![]() It doesn’t matter whether you’re saving for a big purchase, new outfit, rainy day fund, etc. What are the benefits of using one of these free printable savings tracker coloring pages?Ī savings tracker template is a fun way to build your savings account. You simply just start by downloading a visual savings tracker and put it somewhere you check on a regular basis so you will be reminded of your progress towards your savings goals. The total amount you save varies and some challenges you can complete in as little as a few months and some may take an entire year or more.įor example, let’s say you want to build a starter emergency fund. It’s a great way to reach financial goals, especially if you’re saving for many different goals. ![]() ![]() These free printables are digital downloads that you can print out and use to complete a savings challenge. Just one coloring sheet can provide you with a visual aid and help you keep track of your progress. Have a specific goal you need to save for? Well, these free printable savings tracker coloring pages are the perfect way to reach your target savings! Perhaps you’ve added some money goals to your vision board this year and have no idea how you’re going to reach your goal amount. ![]() ![]() Each electron counts as one and so a pair counts as two. Lone Pairs = lone electrons sitting on the atom.Valence electrons = corresponds to the group number of the periodic table (for representative elements).Let’s start with the proper formula and then learn a shortcut. A long, annoying trip to my professor’s office hours enabled me to figure it out, but it was still overwhelmingly TEDIOUS! The formula in my textbook was long, tedious and brutal. ![]() When I first studied formal charge I was lost. Now that you know WHAT we’re studying, let’s see HOW! – That’s where I can help you. If the atom loses negative electrons and therefore has as few as one extra POSITIVE protons in its nucleus, it will carry a net positive charge. If the atom has just one more negative electron, than protons, it will have a net negative charge. An ion is simply an atom or molecule that gained or lost electrons to get a net charge. Think back to general chemistry when you studied ion formation. The answers are yes, yes, yes, and more yes. Which specific atom is responsible for the overall charge?Īnd, what if you’re studying an uncharged molecule – Is it still possible for individual atoms to carry charge despite the net neutrality? Even the negative charge on the hydroxide oxygen is simple to understand.īut what if you have a much larger group of bound atoms with an overall net charge? For example, the negative nitrate or triple negative phosphate. Chloride obviously has a negative charge. This concept is simple enough for small ions. ![]() The sum of formal charges on any molecule or ion results in the net overall charge. So what exactly IS formal charge?įormal charge is the actual charge on an individual atom within a larger molecule or polyatomic ion. Formal charge helps you understand reaction patterns by showing you why a specific atom attacks, and why its ‘victim’ accepts the attack. Yet understanding the nature of Formal Charge is a critical component when it comes to mastering organic chemistry reactions and mechanisms. How can you afford that kind of time when working through a multi-step synthesis? With increase in nuclear charge, the ionisation energy increases across the period while it decreases down the group.Formal Charge is that pesky concept covered early in organic chemistry and somehow never seems to go away.īecause the equation in your textbook is long, confusing, and needlessly annoying. Therefore, the electrons in the outermost valence shell are more firmly held because of which greater ionisation energy is required to remove the electrons. The greater the nuclear charge, the greater is the attraction for the electrons of the outermost shell. Effect of Nuclear Charge on Ionisation Energy in the Periodic Table With increase in nuclear charge, the non-metallic character decreases on moving down the group while it increases across the period. The greater the nuclear charge, the greater is the tendency of elements to gain electrons, hence the non-metallic character of the element increases. Effect of Nuclear Charge on Non-Metallic Characters in the Periodic Table On moving down a group, metallic nature increases with increase in nuclear charge while it decreases across the period. This makes it difficult to remove the electrons from the outermost orbit. The greater the nuclear charge, the greater is the force exerted by the nucleus on the electrons of the outermost orbit. Effect of Nuclear Charge on Metallic Characters in the Periodic Table Therefore, nuclear charge will always increase whether we move down a group or across the period in the periodic table. With increase in nuclear charge, on moving down a group, the atomic size increases while on moving across a period, the atomic size decreases. Effect of Nuclear Charge on Atomic Size in the Periodic TableĪtomic size depends on the nuclear charge as well as the number of shells. ![]() An increase in the nuclear charge will decrease the atomic size as their electrons are attracted towards the nucleus with a greater force, thereby bringing the outermost shell closer to the nucleus. Nuclear charge is the positive charge present in the nucleus of an atom, which is equal to the number of protons in the nucleus, i.e., the atomic number. ![]() What is Nuclear Charge on Periodic Table? ![]() ![]() Plus, the leaves on the trees here have a lighter green color. In the dense forest, there is a large amount of one- and two-block-high grass. ![]() In the habitat of a large number of fireflies, you can find small meadows of two-block-high flowers, such as lilacs, roses, and peonies. You can craft such jars yourself by combining a glass bottle with a firefly. In addition to them, the forest is illuminated by special lanterns on trees and the ground that consist of jars with fireflies. On oak trees, you can often spot new mobs, namely fireflies. For example, there is a twilight oak, which is about the same size as a regular oak, and a twilight pine, which is simply huge in size. There you can find two new types of trees. The Twilight Forest mod has a wide variety of biomes in it. If you want to spawn in a new dimension even after death, you need to sleep on a bed. Another way is to die and end up in the normal world. After you get into another dimension, there will be an identical portal, which is an exit to the Overworld. ![]() You can return from this dimension in 2 ways. After everything is done, the water will take on a purple color, similar to that of the Nether Portal. To activate the portal, throw one diamond into the water, move back a couple of blocks and wait for lightning to strike the water. Then plant flowers along the edges of the pool, no matter if the flowers are the same or different. To do this, make a pool 2 by 2 blocks in size and fill it with water, thereby forming an endless source of water. If you want to get into a new dimension, you need to build a small portal. How to get to a new dimension and come back The Twilight Forest mod adds a new storyline to the game, as well as another dimension with new mobs and bosses. ![]() ![]() So far, I don't know of a more accurate way to fix it from my side, ask the dev from that side if there's anything that could fix it. DEC uses ActorReference.GetActorBase().getSex() to get gender, and I don't know how else to get it. Some mods, for whatever reason, create template NPCs that have the wrong gender assigned to them. Everything after that is smooth, and you shouldn't need to turn DEC off, if you have reason to believe otherwise tell me. Mia's Lair: I think I got all incompatibilities with Mia's lair sorted out, but you might still get a stack dump during the interrogation part, because I haven't added location based detection for that part yet. I cannot find a way to detect that they are slaves, so there is no way to stop them from attacking the player, and some of them were bugged out and could not interact with last time I tried the mod. By TarBaby.Ĭontent Consumers Alternate Starts v1.Currently, the only mod I recommend users not use in combination with DEC is Sky Slavery, which adds male slaves around skyrim. Resizes some of the animation furniture for the ZaZ Animation Pack to better fit the child races (0.755 scale).Ī small change to the SOS Plugin for Racemenu which allows 0.01 sized adjustments and a lower minimum size of 0.1 (original was 1). OSL Aroused - Arousal Reborn OSL Aroused is a framework independent, SKSE based Arousal Framework. !WZcFnarT!FjyZQJQRdAcgjU0qvBcxgH7_tvuXPnFk2a4WeJZ3Dtg !ORswWDAJ!XxSrYdEHfMPAHuDeZhKOWaR7e_uGDhFx2FlLy9FTu-w !7FsWRSyI!meml_vcJSMKr4N_I-EIPJqoRvyugYNe6bGV2A0O7cdo !6IEhDQzD!KP6ujYoeRbJwe9yodX8QizhrOlPgMyGmF7mxDWs_mpM Original mod: SexLab Rape Spell with Victimize Original mod: Sexlab Hentai Pregnancy 1.19f Full mod custom version !iFt2EQRA!Uv9I8DvWFc0PNlnEcgZYnVoPxs4HZlldY3NVhKxYS9o !3d0ESBbQ!hlfWHPK_TxhfqXHp7FbajejiQhU2c_PokMLGHli8lNY SexLab Aroused Creatures v04.0 Beta 05 Patch !HIETGAhT!D3Dsnuwo_dbxQ7wFUD3iUNS_8IFzL_pdoK71DIVMqlE SD+ (Sanguines Debauchery Enhanced) v3.6.1 Child Patch !KIEGXagS!YVusknHsbHV94W0YIVhqaVpzqRfKgECKHG4aGwdSqms !SUkEACqR!PpLCu5f83FnrpUKwZ1HaCmvfbwT05urqboBILG0LrNE !aVdW3ZxJ!6f9oIPA86T6TKufTJcu0C12ysnBtA5sSDvW84MOVbzo Original mod: Mia's Lair v6.2 (aka Sexlab Sex Slaves 62) Patch Mia's Lair v6.1f (aka Sexlab Sex Slaves 21) Patch !7U93yIaD!pJa6RBaV6wvMbtFp6eEnxBRU56u-MIrPP9Uf7WAeTkc Original mod: Dripping When Aroused Patch !jJ1VlZST!gWfYk36cPoY6mqutR7KjVDnCXKvXDUaAW5kymFz82k8ĭevious Devices - Integration 3.0, 3.1, 3.3, 4.0 Patch Removes the child flag from children that are born.ĭefeat 5.3.5 Patch (Only for Sexlab 1.60+)ĭevious Devices - More Devious Quest V0.905 Patch V2 !iQNRWCCL!7DpmL0UVSfVRkOkH2-k1iWVnhnrJ1wglR7gLuFlTY_0 !2EtkUK6K!dfzrFQAv3JXWmyeglOxjtu42qG5_k6YmnuuMbN6XZAĬontains complex checks against children, so you'll need this even if the child flag has been removed from your race(s).Ĭhildren + Soul Gems (Hentai Pregnancy Addon - RSChildren 1.5 Patch Note: you can download additional animations and register them with FNIS. Not actually recommended as this is quite an old mod, Sexlab is much more modern. Dont want to spend hours figuring out how to install SL for Anniversary Edition x.640 Heres all the essential mods you need. !mIkzFBhI!2HBWzIT8sFDB-ByzV0HSuRSPosFFv1SVb2ZhkKU1lf8 Needed to make sex animations work with child races. Patches are for specific mod versions only!Īlso, most specific SexLab patches are ONLY needed for RCotS, as Skykids does not leave the isChild flag turned on 2.40 SexLab Beastess: Loli Artwork Replacers + Follower Body Patch.2.39 SexLab Achievement: Loli Artwork Replacers.2.38 Bathing Beauties or Beefcakes Luxury Suite v6.2 Patch.2.37 Content Consumers Alternate Starts v1.3 Patch.2.31 Strip Spell 0.4 Cheat Version Patch.2.26 Sexlab Hentai Pregnancy 1.19f Full mod custom version.2.21 SexLab Aroused Creatures v04.0 Beta 05 Patch.2.19 SD+ (Sanguines Debauchery Enhanced) v3.6.1 Child Patch.2.15 Mia's Lair v6.2 (aka Sexlab Sex Slaves 62) Patch.2.14 Mia's Lair v6.1f (aka Sexlab Sex Slaves 21) Patch.2.13 Hentai Creatures Expanded 1.2 Patch.2.7 Devious Devices - More Devious Quest V0.905 Patch V2.2.5 Children + Soul Gems (Hentai Pregnancy Addon - RSChildren 1.5 Patch.2.1 SexLab 1.62 All-in-one Kids Package. ![]() ![]() ![]() This album is similiar to the great 'Steal Your Face', (again, don't listen to the critics, there's nothing wrong with that album), however, the band aren't as 'tight' and there's more jamming, (nothing like the earlier stuff though, justy general extended solo's etc). Great sound, (occasionally the odd vocal is quite against the instruments yet this is neither here nor there), fab playing, especially Jerry's guitar, as well as great vocals. This is by far their most 'upbeat' and 'uptempo' album. It's the electric brother to the aforementioned album. It captured the post Godcheaux Dead on fine form. For those of you who don't know, this album was released in 1981, just after 'Reckoning'. I personally think giving this album less than 4 stars is insane, especially given the general acclaim aimed at 'With a Net' this is far superior. ![]() I bought with trepidation this and 'Reckoning' as I gear towards 70's albums and not 1980's and some of the reviews surrounding this particular album weren't too great, (as always though, don't listen to people and critics - it's down to everyones taste. I now have every 'official' live release from the band as well as a few of the archive releases. They are, quite simply, the best live act i've ever heard. The matrix not only captures the audience and gives us some feel for the atmosphere of the Providence Civic Center, but it also replaces the board’s rough Stranger with an audience patch, giving us a much more copacetic recording of this ripping version.As someone who just 12 months ago knew nothing about this band, (I knew they were a band yet for some reason I always thought they were mordernish, like the Stone Roses in style!!!), I know adored these guys. Then don’t miss Bobby cheesing out in the Good Lovin’ closer before the US Blues encore caps it all.Ĭharlie Miller reworked the soundboard to this one, giving a crispy base for Hunter Seamons’s matrix that we have cued up here. The Other One eventually heads into a well-conceived Wharf Rat> GDTRFB. This percussive performance is like a tocsin call from the ancient past, as Mickey and Billy create some alternative, but vaguely familiar world. From the Drums, a ridiculous Space flows forth, distressingly alien and then suddenly luscious and comforting as it bubbles forth, gathering into a steamy Other One. After that, we get a frenetic Eyes that sets up a segues from Jerry’s blistering raw energy on the guitar to the immense power of the drummers as they break out the earthquake drum after the rest of the boys leave the stage. And that tasty nugget leads the way to a ferocious Estimated that is replete with earthy jams. ![]() But things really kick off a tune later with a fiesty Supplication jam that is as fine as it is rare. The second set, previously released as one of the Download Series, is a luscious tour-de-force, beginning with a powerful Samson. And while the rest of the set is delightful, the highlights of the first half have to be the Peggy-O and Althea, with Jerry just killing it on both. The band kicks things off with a super hot Stranger, and this despite the fact that they had just played the tune the night before. ![]() |
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